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srijeda, 20. lipnja 2012.

Way to Create Biofuels



Way to Create Biofuels

Is there a new path to biofuels hiding in a handful of dirt? 
Lawrence Berkeley National Laboratory (Berkeley Lab) biologist Steve Singer leads a group that wants to find out. They’re exploring whether a common soil bacterium can be engineered to produce liquid transportation fuels much more efficiently than the ways in which advanced biofuels are made today.

The scientists are working with a bacterium called Ralstonia eutropha. It naturally uses hydrogen as an energy source to convert CO2 into various organic compounds.

The group hopes to capitalize on the bacteria’s capabilities and tweak it to produce advanced biofuels that are drop-in replacements for diesel and jet fuel. The process would be powered only by hydrogen and electricity from renewable sources such as solar or wind.

The goal is a biofuel—or electrofuel, as this new approach is called—that doesn’t require photosynthesis.

Why is this important? Most methods used to produce advanced biofuels, such as from biomass and algae, rely on photosynthesis. But it turns out that photosynthesis isn’t very efficient when it comes to making biofuel. Energy is lost as photons from the sun are converted to stored chemical energy in a plant, which is then converted to a fuel.

“We’re after a more direct way,” says Singer, who holds appointments with Berkeley Lab’s Earth Sciences Division and with the Joint BioEnergy Institute (JBEI), a multi-institutional partnership led by Berkeley Lab.

“We want to bypass photosynthesis by using a microbe that uses hydrogen and electricity to convert CO2 into a fuel,” he adds.

Widespread use of electrofuels would also reduce demands for land, water, and fertilizer that are traditionally required to produce biofuels.

Berkeley Lab’s $3.4 million electrofuel project was funded in 2010 by DOE’s Advanced Research Projects Agency-Energy (ARPA-E) program, which focuses on “high risk, high payoff concepts—technologies promising genuine transformation in the ways we generate, store and utilize energy.”

That pretty much describes electrofuels. ARPA-E estimates the technology has the potential to be ten times more efficient than current biofuel production methods. But electrofuels are currently confined to lab-scale tests. A lot of obstacles must be overcome before you’ll see it at the pump.

Fortunately, research is underway. The Berkeley Lab project is one of thirteen electrofuel projects sponsored by ARPA-E. And earlier this year, ARPA-E issued a request for information focused on the commercialization of the technology.

Singer’s group includes scientists from Virginia-based Logos Technologies and the University of California at Berkeley. The project’s co-principal investigators are Harry Beller, Swapnil Chhabra, and Nathan Hillson, who are also with Berkeley Lab and JBEI; Chris Chang, a UC Berkeley chemist and a faculty scientist with Berkeley Lab’s Chemical Sciences Division; and Dan MacEachran of Logos Technologies.

The scientists chose to work with R. eutropha because the bacterium is well understood and it’s already used industrially to make bioplastics.

They’re creating engineered strains of the bacterium at JBEI, all aimed at improving its ability to produce hydrocarbons. This work involves re-routing metabolic pathways in the bacteria. It also involves adding pathways from other microorganisms, such as a pathway engineered in Escherichia coli to produce medium-chain methyl ketones, which are naturally occurring compounds that have cetane numbers similar to those of typical diesel fuel.

The group is also pursuing two parallel paths to further boost production.

In the first approach, Logos Technologies is developing a two-liter bioelectrochemical reactor, which is a conventional fermentation vessel fitted with electrodes. The vessel starts with a mixture of bacteria, CO2, and water. Electricity splits the water into oxygen and hydrogen. The bacteria then use energy from the hydrogen to wrest carbon from CO2 and convert it to hydrocarbons, which migrate to the water’s surface. The scientists hope to skim the first batch of biofuel from the bioreactor in about one year.

In the second approach, the scientists want to transform the bacteria into self-reliant, biofuel-making machines. With help from Chris Chang, they’re developing ways to tether electrocatalysts to the bacteria’s surface. These catalysts use electricity to generate hydrogen in the presence of water.

The idea is to give the bacteria the ability to produce much of their own energy source. If the approach works, the only ingredients the bacteria will need to produce biofuel would be CO2, electricity, and water.

The scientists are now developing ways to attach these catalysts to electrodes and to the surface of the bacteria.

“We’re at the proof-of-principle stage in many ways with this research, but the concept has a lot of potential, so we’re eager to see where we can take this,” says Singer.
CCRES
 special thanks to 
Lawrence Berkeley National Laboratory
Croatian Center of Renewable Energy Sources (CCRES)

petak, 18. svibnja 2012.

Nor Cal Biodiesel


CCRES promotes Nor Cal Biodiesel
Nor Cal Biodiesel currently offer two models to choose from: the BioPro190 and the larger BioPro380.
BioPro190

BioPro190 General Information and Specifications
  • Dimensions: 21"w x 21"d x 67"h. Overall height adjustable +/- 2”
  • Weight: 325 Lbs. (empty).
  • Capacity: 50 gallons oil yields 50 gallons of finished fuel.
                   10 gallons methanol - yields approx. 10 gallons glycerin.
  • Construction: TIG welded 304 stainless steel body; Powder coated carbon steel covers.
  • Fittings: 304 stainless steel or glass filled polypropylene.
  • Electrical: 110 VAC / 15 Amp Circuit.
  • Controls: AUTO mode controlled by program logic controller;
                   Start button initiates completely automated process;
                   MANUAL mode controlled by switch actuation.
  • Reaction Method: Acid-catalyzed esterification of free fatty acids
                   Then base-catalyzed transesterification of triglycerides;
  • Wash Method: Triple-stage turbulent water wash.
                   1) Mist Spray, 2) Mist & Agitation, 3) Mist & Agitation
  • Batch Time: Reaction Time – approximately 8 hrs;
                   Initial settling - 16 hrs;
                   Water wash – approximately 14 hrs;
                   Drying cycle - Approx 10 hrs:
  • Total Processing Time: Approx. 48 hours start to finish.
Items You Will Need To Get Started:
  • 50 Gallons of new or used filtered vegetable oil or oil derived from animal fats
  • 400 micron, or finer, filter to strain the oil
  • 10 Gallons of methanol (racing fuel)
  • For your safety and convenience, we suggest obtaining a methanol compatible and an oil/grease
    compatible transfer pump
  • 1520 grams (3.41 lbs) Sodium Hydroxide - NaOH or 2350 (5.17 lbs) grams Potassium Hydroxide - KOH
  • 190 mL (6.43 oz) Sulfuric Acid (93% Purity or higher) - Do not use common battery acid
  • 50 Gallons of fresh, standing water
  • 50 Gallon container or receptacle for “water in”
  • 50 Gallon container or receptacle to collect the wash water – or connect directly to a drain.
  • Air tight storage containers for methanol (typically, a 55-gallon drum), catalyst potash, and sulfuric acid
  • Protective gloves, face mask, apron, and safety goggles (included)
  • Transfer hoses, scales, and measuring cups (included)
  • (1) 110-120 volt / 15 amp & (1) 220 volt / 30 amp AC power source 
  BioPro380
BioPro380 General Information and Specifications
  • Dimensions: 64"w x 34"d x 91"h. Overall height adjustable +/- 2”
  • Weight: Approximately 675 Lbs. (empty).
  • Capacity: 100 gallons oil yields up to 100 gallons (380 liters) of finished fuel
  • Batch Sizes: - Capable of processing 50, 75, or 100 gallons of oil feedstock (190, 284, or 380 liters).
  • Construction: TIG welded 304 stainless steel body; Powder coated carbon steel covers.
  • Electrical: 220 VAC / 30 AMP & 110 VAC / 15 Amp Circuit. Dedicated Circuits are preferred but not required.
  • Controls: AUTO mode controlled by program logic controller;
                   Start button initiates the automated process;
                   MANUAL mode controlled by switch actuation.
  • Reaction Method: Acid-catalyzed esterification of free fatty acids
                   Then base-catalyzed transesterification of triglycerides;
  • Method: Triple-stage turbulent water wash.
                   1) Mist Spray, 2) Mist & Agitation, 3) Mist & Agitation
  • Batch Time: Reaction Time – approximately 8 hrs;
                   Initial settling - 16 hrs;
                   Water wash –(total three (3) cycles, approximately14 hrs;
                   Drying cycle - Approx 10 hrs:
  • Total Processing Time: Approx. 48 hours start to finish.
Items You Will Need To Get Started:
  • 100 Gallons of new or used filtered vegetable oil or oil derived from animal fats (triglycerides
  • Minimum 400 micron, or finer, filter to strain the oil
  • 20 Gallons of methanol (racing fuel; 99.99% pure)
  • 3040 grams Lye (Sodium Hydroxide - NaOH) or 4700 grams Caustic Potash (Potassium Hydroxide - KOH)* *Recommended
  • 380 mL Sulfuric Acid (93% Purity or higher) - Not common battery acid
  • 100 Gallons of fresh standing water (can also be connected directly to a pressurized water line)
  • 100 Gallon container for water in (or connect to a clean, pressurized water source)
  • 100 Gallon container for water out (or connect directly to a drain)
  • Air tight storage containers for methanol, lye/caustic potash, and sulfuric acid
  • Protective gloves, face mask, apron, and safety goggles (included)
  • Transfer hoses, scales, and measuring cups (included)
  • For your safety and convenience, we suggest obtaining a methanol transfer and oil/grease transfer pump
  • (1) 110-120 volt / 15 amp & (1) 220 volt / 30 amp AC power source 
 Since it's introduction, the BioPro line of products have steadily found their way into the hands of many an independent souls.
 Click on the links below to read about
CONTACT Nor Cal Biodiesel
Please feel free to contact  Nor Cal Biodiesel for additional information regarding our products or services.
 
 Nor Cal Biodiesel also welcome any comments or suggestions regarding  products, web site and overall experience regarding your initial interaction with Nor Cal Biodiesel.
General Inquiries and Sales Information info@norcalbio.com
Projects, Business Development or Specific Requests danny@norcalbio.com
Nor Cal Biodiese web site : http://norcalbio.com/index.html
For any additional information, please contact 
Danny Lesa, telephone 707-766-9782 
CROATIAN CENTER of RENEWABLE ENERGY SOURCES
 (CCRES)

petak, 11. svibnja 2012.

The Pentagon, the largest U.S. consumer of fuel goes green



 
Last month U.S. Army Energy Initiatives Task Force (AEITF) issued a draft request for proposals (Draft RFP) renewable energy contracts.
 
What’s on offer? Over the next decade, an impressive $7 billion. During the AEITF’s pre-solicitation phase, the Draft RFP is designed to gather information from potential bidders to assist the AEITF to develop a formal Request for Proposal (RFP) that it intends to issue later this year.
 
The United States Armed Forces, which currently fuels 77 percent of its machinery with petroleum-based fuel, has announced an aggressive goal, to be petroleum free by 2040. The Air Force intends to use biofuels for 50 percent of its domestic aviation needs by 2016.
 
A 2011 Pew Charitable Trusts report, "From Barracks to the Battlefield: Clean Energy Innovation and America's Armed Forces" reported that Department of Defense clean energy investments increased 300 percent between 2006 and 2009 - from $400 million to $1.2 billion - and are projected at $10 billion annually by 2030, adding that that by 2015, the Pentagon will be spending $2.25 billion each year to harness clean energy technologies for air, land and sea vehicles.
 
Driving the Pentagon’s green drive is Executive Order 13423, which mandates that the Department of Defense achieve a 30 percent reduction in non-tactical fleet fossil fuel use by 2020.
 
A second key piece of legislation driving the Pentagon’s mandate is the Renewable Fuel Standard, which Congress enacted in 2005 as part of the Energy Policy Act, amending it in the 2007 Energy Independence and Security Act. The amended standard mandated that by 2022 the consumption volume of the renewable fuels should consist of: 15 billion gallons of conventional biofuels, mainly corn-grain ethanol; 1 billion gallons of biomass-based diesel fuel; 4 billion gallons of advanced renewable biofuels, other than ethanol derived from cornstarch, that achieve a life-cycle greenhouse gas threshold of at least 50 percent; and 16 billion gallons of cellulosic biofuels produced from wood, grasses, or non-edible plant parts, such as corn stalks and wheat straw.
 
The draft AEITF RFP marks the beginning of the AEITF's plan to develop a large, coordinated procurement process for renewables. The AEITF's new program was developed in response to a National Defense Authorization Act that requires Department of Defense facilities to derive at least 25 percent of the electricity they consume from renewable energy by 2025, and a Department of Defense "Net Zero Energy" initiative, which challenges DOD installations to produce more energy than they consume, with emphasis on the use of renewable energy and alternative fuels.
 
So, what is holding back the production of commercially viable amounts of biofuels? Key barriers to achieving the renewable fuel mandate are the high cost of producing biofuels compared with petroleum-based fuels uncertainties in future biofuel markets, a lack of subsidies and crop insurance, along with a shortage of significant investment.
 
These factors have combined to produce a “perfect storm” up to now for biofuel producers, resulting in “designer fuels” of high cost for Pentagon testing.
 
To give but one example.
 
In October 2010 the Navy purchased 20,055 gallons of algae biofuel at an eye-watering cost of $424/gallon.  Nevertheless, the contract was one of the biggest U.S. purchases of a non-corn ethanol biofuel up to that time. A year later, the Navy reportedly spent $12 million for 450,000 gallons of biofuel. The bad news was that the biofuel’s cost worked out to around $26.67 per gallon, roughly six times the current cost of traditional gas.
 
The good news?  In a single year, the cost per gallon of biofuel plummeted by a factor of 15.9.
 
Furthermore, $7 billion in funding is likely to prove a significant game changer in the field.
 
So, where does this leave the investor? No single biofuel source, from jatropha, algae or camelina has yet to emerge as the clear winner, though the last seems most likely to emerge as the frontrunner. Accordingly, investors must do their homework and seek out potential winners.
 
For those wishing to broaden their portfolios, two websites will prove of immense value.
 
The first is www.usa.gov, the federal government’s website for the U.S. government, where one can come to grips with federal legislation and Pentagon initiatives.
 
The second is Jim Lane’s http://www.biofuelsdigest.com/, the self-proclaimed “world’s most widely read biofuels daily.” While the site has an element of tub-thumping boosterism, it nevertheless remains an immensely valuable source of information about the biofuel market and the major players.
 
It is important to remember how different the biofuels picture is now from even a year ago. The Pentagon, the largest U.S. consumer of fuel, is now under pressure to meet the various federal mandates, and careers and promotions hang in the balance.
 CCRES special thanks to 
John C.K. Daly ,
U.S.-Central Asia Biofuels Ltd
Croatian Center of Renewable Energy Sources (CCRES)

ponedjeljak, 7. svibnja 2012.

CCRES - BIODIESEL



CROATIAN CENTER of RENEWABLE ENERGY SOURCES 
(CCRES)

Biodiesel

The Popular Biofuel

The fuels obtained from biomass materials, like the waste generated by plants, animals and humans beings, are called as the biofuels. The biofuels are well known alternative fuels used for the production of heat and electricity and also driving the vehicles. The biomass is considered to be a type of renewable sources of energy since it is available in unlimited quantity and will continue to do so for unlimited period of time. One of the most popular types of biofuels is biodiesel.

Biodiesel is obtained from the fresh or used vegetable oil and animal fats by the process called transesterification. Efforts are being made to obtain biodiesel from waste grease and oils. The modern methods have been discovered to obtain biodiesel from algae as well.

Early Diesel Engine and Biodiesel

Rudolph Diesel had invented diesel engine in the period dating back to 1890. Though the present diesel engine is being run entirely on petroleum diesel fuel, in the days of invention itself Rudolph had envisioned that his engine could be powered by vegetable oil and could be used in the remote areas of farmlands where petroleum diesel is not available, but where the vegetable oil can be obtained easily from the plants. This way the farmers would be able to run the vehicles used by them for farming by using the vegetable oil. Rudolph had carried out extensive research to run his engine on vegetable oil.

In fact biodiesel was one of the earliest fuels used for running the engines of the automobiles.

After Rudolph's death in 1913, the gasoline including diesel became much cheaper so the design of Rudolph's engine was modified so that it can run on petroleum diesel. It is indeed interesting to know that after almost 100 years, the engine developed by Rudolph is now being run on the same fuel i.e. biodiesel made from vegetable oil, as per its original vision.

Biodiesel used for Running Vehicles

As mentioned earlier, the original diesel engine was designed to run on biodiesel or vegetable oil. For all the vehicles manufactured after the year 1993 biodiesel can be used as the fuel in all diesel engines without making any changes in the fuel injection system. When one uses the biodiesel there may be very little or no change in the performance of the engine.

The properties of biodiesel are very similar to traditional diesel obtained from the crude oil. While the combustion of traditional diesel produces lots of air pollution and toxic gases, the burning of biodiesel is clean and it does not cause any environmental pollution.

Biodiesel can be used as the fuel for automobiles in the pure form or it can be mixed with petroleum diesel in various proportions to form the blends. The two most commonly used blends of biodiesel are B20 and B100. B20 is the blend of 20% of biodiesel and remaining percentage of petroleum diesel and is the most widely used blend in US. It also meets all the regulations under the Energy Policy Act (EPAct) documented in 1992. Most of the other fuel blends containing lesser than 20% of biodiesel can also used for the running the vehicles. B100 is the pure form of biodiesel and it can be used in the diesel engines only after making certain changes in the hosesand gaskets of the engine.

Controversies Related to Biodiesel

Now that biodiesel is being blended with petroleum diesel and is being used as the fuel, its demand is fast increasing. A number of farmers are tempted to grow the crops that would yield biodiesel at the cost of the food crops. Instead of using the fertilizers, pesticides and energy for the food crops, farmers are using them for the biodiesel crops. This leads to not only the misuse of the limited resources but also shortage of the food crops.

In some parts of the world large areas of forests have been cut down to grow sugarcane for ethanol and soybeans and palm-oil tress for making biodiesel. US government is making efforts to make sure the farming for biomass materials does not competes with the farming of food crops and that the farming of biomass would require lesser fertilizers and pesticides. A number of other sources for biodiesel are also being explored like used oils and greases and algae.

Benefits of Biodiesel

Here are some of the benefits of using biodiesel as a fuel:

1) Biodiesel can be easily blended with petroleum diesel and the mixture can be readily used for running the vehicles without carrying out any changes in the engine.

2) Though the properties of biodiesel are same as the petroleum diesel, the combustion of biodiesel produces no greenhouse and other gases that would harm the environment.

As the proportion of biodiesel increases in the petroleum diesel blend, its tendency to generate pollution reduces.

3) Biodiesel is made from plant oil and vegetable fats, which are biodegradable, so they can be easily disposed of. When biodiesel is leaked or split it does not harm the environment.

4) The country manufacturing and using biodiesel is less dependent on other countries for their fuel requirements. Biodiesel has the potential to make countries self-reliant for their future fuel requirements. Further, since biodiesel is obtained from the renewable source of energy, it could be considered an important fuel for future planning.


CCRES 
special thanks to   
Escapeartist, Inc
 CROATIAN CENTER of RENEWABLE ENERGY SOURCES 
(CCRES)